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l-Phenylalanine l-Phenylalaninium Formate (LPPF) is an organic nonlinear optical crystal with molecular formula C9H11NO2·C9H12NO2+·CHO2−, was grown by solution growth, slow evaporation method. Single crystal XRD reveals that the title compound crystallizes in monoclinic system with the space group P21. The presence of functional groups was identified by FT-IR spectrum. UV–visible spectrum analysis...