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Water-repellent finishing of cotton fabrics was carried out using fluorine-free functionalized silsesquioxanes. The modification was performed in two stages: (i) preparation of alkylfunctionalized silsesquioxanes bearing additional triethoxysilyl groups by way of a photochemical thiol-ene click reaction, and (ii) modification of the cotton fibers with these silsesquioxane derivatives. Different ratios...
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