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The oxidation of four Ni–xSi–6Al alloys (x=0,2,4 and 6at.%) has been studied at 1273K under 0.1MPa O 2 . Silicon exerts the third-element effect by reducing the critical Al content needed for the transition from its internal to its external oxidation with respect to Ni–Al alloys. This result is interpreted by extending to ternary alloys Wagner’s criterion for the same transition in binary...
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