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Lanthanum(III) was immobilized on various zeolite supports by simple cation exchange. The resulting materials were tested in the disproportionation of H 2 O 2 into singlet molecular oxygen ( 1 O 2 ). The rate of H 2 O 2 disproportionation and the reaction of the formed 1 O 2 with citronellol as a typical olefinic substrate were strongly...
Seventeen organic solvents are screened as reaction media to conduct the molybdate-catalyzed disproportionation of hydrogen peroxide into singlet molecular oxygen, 1 O 2 ( 1 Δ g ). The solvents are investigated by resorting to the detection of the infra-red luminescence of 1 O 2 at 1270 nm. Preparative peroxidations of representative substrates are carried...
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