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(ortho)-3,3'-Diphenyl-2,2'-bithiophene is shown to exhibit a solid-state helical conformation that is consistent with MMFF predictions of structure. The optical, electronic, and conformational properties of this compound are examined, and the results are commensurate with a helical building block capable of exhibiting redox-induced conformational changes along the long molecular axis. Such a property...
Herein we report a laser micrometer-based technique to measure real-time dimensional changes occurring orthogonal to the surface of adsorbed polymer films. With particular regard to electromechanical actuators, this technique compliments the widely used bending beam method (BBM). Advantages of this technique include facile integration of commercially available hardware, minimal restrictions on electrode...
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