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Ultrathin and self-supported films of sodium dodecyl sulfate (SDS) constituted of two surfactant monolayers separated by an interstitial layer of water have been studied using a confocal micro-Raman spectrometer. It appears to be very convenient to follow the draining of water and later on to characterize the final equilibrium state of the film with thicknesses ranging from 100 to less than 50 9,...
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