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The bacterial repair enzyme MutT hydrolyzes the damaged nucleotide OdGTP (the 5′-triphosphate derivative of 8-oxo-2′-deoxyguanosine; OdG), which is a known mutagen and has been linked to antibacterial action. Previous work has indicated important roles for the C8-oxygen, N7-hydrogen, and C2-exocyclic amine during OdGTP recognition by MutT. In order to gain a more nuanced understanding of the contribution...
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