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Molecular systems that exhibit controlled or coordinated rotary motion are discussed in this chapter. These systems represent a reproduction of a variety of macroscopic mechanical devices on the molecular scale. From gears to a motor, passing through a turnstile, a brake and a ratchet, we describe their design, synthesis and dynamic behavior. The importance of molecular motors in the biological realm...
"In my opinion, this book provides deep insight into this fascinating, challenging, and increasingly important field.Are you interested in molecular machines and looking for a comprehensive book to learn the important physical paradigms and synthetic strategies? Do you teach molecular machines in a chemistry or engineering course at a college and would like to include the usual and some unusual...
With the objective of establishing why reaction of the proposed molecular motors 7 and 22 with carbonyldiimidazole and phosgene does not result in unidirectional rotation, N-ethyl-2-[4-(N,N-dimethylamino)-2-pyridinyl]benzenamine [28, 2-(2-(ethylamino)phenyl)DMAP] was examined as a model substrate. The synthesis of 28 is described. Compound 28 was found to react with phosgene to give the unexpectedly...
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