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Oxygen reduction and ethanol oxidation reactions were studied on Au(111), Pt(111) and Ir(111) in alkaline solutions containing sodium and/or lithium cations. By keeping the same (111) surface orientation and exploring oxophilicity trends and non-covalent interactions between OHad and alkali metal cations (AMCn+), we were able to gain deep insights into the multiple roles that OHad plays in these important...
Oxidation of propenol on nanostructured pulse plated Ni and NiZn alloys in alkaline solution gives the corresponding aldehyde, propenal, as the major product. The process is redox mediated by the NiOOH/Ni(OH) 2 couple and starts as soon as NiOOH is formed on the surface. Depending on the applied potential, propenol oxidation takes place in parallel with water oxidation. The latter requires...
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