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The aqueous chemistry of vanadium with physiologically relevant ligands constitutes a subject of burgeoning research, extending from bacterial metalloenzymic functions to human-health physiology. Vanadium, in the form of VCl 3 and V 2 O 5, reacted expediently with citric acid, in a 1:2 molar ratio in water at pH~4, and, in the presence of various cations, afforded crystalline...
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