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The theoretical approach to the understanding of the NMR parameters in paramagnetic exchange coupled dimers is discussed and simplified formulas are provided. The effect of magnetic coupling on electron relaxation times in magnetic coupled heterodimetallic systems is also discussed. The 1H NMR spectra of two oxidized and reduced Fe2S2-ferredoxins are interpreted and structural information is obtained...
The spectral and magnetic properties of simple high spin cobalt(II) complexes are reviewed with the aim of showing how it is possible to relate the experimental data to the electronic structure and the coordination geometry of the complexes. It is hoped that this may be of help to all researchers who need to characterize cobalt(II) complexes or use cobalt(II) as a spectroscopic probe. The data relative...
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