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Well‐controlled core–shell hierarchical nanostructures based on oxyfluoride and hydroxide are for the first time rationally designed and synthesized via a simple solvothermal and chemical precipitation route, in which FeOF nanorod acts as core and porous Ni(OH)2 nanosheets as shell. When evaluated as electrodes for supercapacitors, a high specific capacitance of 1452 F g−1 can be obtained at a current...
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