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With their hydrolytic, optical and magnetic properties, lanthanide ions (Ln3+) are versatile probes for nucleic acids. In addition, nucleotide-coordinated Ln3+ ions form useful nanoparticles. However, the thermodynamic basis of their interaction is still lacking. In this work, isothermal titration calorimetry (ITC) is used to study the binding between nucleotides and 14 different Ln3+ ions. Ln3+ interacts...
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