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Tartaric acid reacts spontaneously with triethoxysilane (HTES) liberating hydrogen gas, but alkyl- or arylhydrosilanes are essentially inert under these conditions. Other α-hydroxyacids reacted similarly with HTES. The reaction of tartaric acid in tetrahydrofuran is a second order process, consistent with a reaction pathway involving first transesterification of HTES by tartaric acid and subsequent...
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