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Thermal decompositions of the trans-[Co(en)2Cl2]Cl and cis-[Co(en)2Cl2]Cl complex isomers have been studied using the TG–FTIR and TG–DSC–MS techniques. The measurements were carried out in argon atmosphere over the temperature range 293–873 K. The influence of the configurational geometry on the pathways of thermal transformations was discussed. Furthermore, kinetic studies on the reaction of the...
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