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Ein oder zwei stabförmige Bissulfonat‐Brückenliganden wurden durch positionsselektive Verdrängung innerer TfO−‐Liganden in eine selbstorganisierte HgII‐Kapsel eingebaut. Durch einen Ligandenaustausch der verbleibenden inneren TfO−‐Liganden wurden TsO−‐Liganden im Innern der resultierenden Kapsel angeordnet, in welcher der/die Bissulfonat‐Ligand(en) zwei gegenüberliegende HgII‐Ecken verbrücken (siehe...
Interior decorating in nanospace: One or two rod‐shaped bissulfonate bridging ligands were incorporated into a self‐assembled HgII capsule by the site‐selective replacement of inner TfO− ligands. TsO− ligands were arranged inside the resulting capsule, in which the bissulfonate ligand(s) connected two opposite HgII vertices, by ligand exchange of the remaining inner TfO− ligands (see picture). Tf=trifluoromethanesulfonyl,...
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